AmDel Services' medical sales force will use the vehicles which have been supplied by Easycar Contracts on a 12-month, 12,000-mile contract hire agreement.
Managing director Duncan Morris said: 'We needed these cars in a hurry and Easycar Contracts and Citroen were able to come up with the right financial and vehicle package at very short notice.
'The Citroen Picasso is ideal for our sales force, who are mainly parents with young children.
'These cars are well equipped and are versatile enough for both business goods and young family.'
The new fleet includes 2.0HDi models and 2.0i 16v automatics.